Covalent superconductor

Parts of a high pressure cell after the synthesis of heavily boron doped superconducting diamond. The diamond (black ball) is located between two graphite heaters

Covalent superconductors are superconducting materials where the atoms are linked by covalent bonds. The first such material was boron-doped synthetic diamond grown by the high-pressure high-temperature (HPHT) method.[1] The discovery had no practical importance, but surprised most scientists as superconductivity had not been observed in covalent semiconductors, including diamond and silicon.

  1. ^ E. A. Ekimov; V. A. Sidorov; E. D. Bauer; N. N. Mel'nik; N. J. Curro; J. D. Thompson; S. M. Stishov (2004). "Superconductivity in diamond". Nature. 428 (6982): 542–545. arXiv:cond-mat/0404156. Bibcode:2004Natur.428..542E. doi:10.1038/nature02449. PMID 15057827. S2CID 4423950.
    L. Boeri, J. Kortus and O. K. Andersen "Three-Dimensional MgB2-Type Superconductivity in Hole-Doped Diamond",
    K.-W. Lee and W. E. Pickett "Superconductivity in Boron-Doped Diamond"[permanent dead link],
    X. Blase, Ch. Adessi and D. Connetable "Role of the Dopant in the Superconductivity of Diamond"[permanent dead link],
    E. Bustarret et al. "Dependence of the Superconducting Transition Temperature on the Doping Level in Single-Crystalline Diamond Films"[permanent dead link] – free download

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