Diethyl selenide

Diethyl selenide
3D model of Diethyl selenide
skeletal model of Diethyl selenide
Names
Preferred IUPAC name
(Ethylselanyl)ethane
Other names
Ethyl selenide
Identifiers
3D model (JSmol)
ChemSpider
UN number 2630
  • InChI=1S/C4H10Se/c1-3-5-4-2/h3-4H2,1-2H3
    Key: ALCDAWARCQFJBA-UHFFFAOYSA-N
  • CC[Se]CC
Properties
C4H10Se
Molar mass 137.09 g/mol
Appearance colorless liquid
Density 1.232 g/ml
Melting point −87 °C (−125 °F; 186 K)
Boiling point 108 °C (226 °F; 381 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammability, toxicity
GHS labelling:
GHS02: FlammableGHS06: ToxicGHS05: CorrosiveGHS09: Environmental hazardGHS08: Health hazard
Danger
H225, H301, H331, H373, H410
P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P273, P280, P301+P310, P303+P361+P353, P304+P340, P311, P314, P321, P330, P370+P378, P391, P403+P233, P403+P235, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasolineInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
3
1
Flash point 22 °C (72 °F; 295 K)
Not available
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Diethyl selenide is an organoselenium compound with the formula C
4
H
10
Se
. First reported in 1836, it was the first organoselenium compound to be discovered.[1][2] It is the selenium analogue of diethyl ether. It has a strong and unpleasant smell.

  1. ^ Mukherjee, Anna J.; Zade, Sanjio S.; Singh, Harkesh B.; Sunoj, Raghavan B. (2010). "Organoselenium Chemistry: Role of Intramolecular Interactions". Chemical Reviews. 110 (7): 4357–4416. doi:10.1021/cr900352j. PMID 20384363.
  2. ^ Löwig, C. J. (1836). "Ueber schwefelwasserstoff—und selenwasserstoffäther" [About hydrogen sulfide and selenium hydrogen ether]. Annalen der Physik. 37 (3): 550–553. Bibcode:1836AnP...113..550L. doi:10.1002/andp.18361130315.

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