Fluorite

Fluorite
Deep green isolated fluorite crystal resembling a truncated octahedron, set upon a micaceous matrix, from Erongo Mountain, Erongo Region, Namibia (overall size: 50 mm × 27 mm, crystal size: 19 mm wide, 30 g)
General
CategoryHalide mineral
Formula
(repeating unit)
CaF2
IMA symbolFlr[1]
Strunz classification3.AB.25
Crystal systemIsometric
Crystal classHexoctahedral (m3m)
H–M symbol: (4/m 3 2/m)
(cF12)
Space groupFm3m (No. 225)
Unit cella = 5.4626 Å; Z = 4
Identification
ColorColorless, although samples are often deeply colored owing to impurities; Purple, lilac, golden-yellow, green, blue, pink, champagne, brown.
Crystal habitWell-formed coarse sized crystals; also nodular, botryoidal, rarely columnar or fibrous; granular, massive
TwinningCommon on {111}, interpenetrant, flattened
CleavageOctahedral, perfect on {111}, parting on {011}
FractureSubconchoidal to uneven
TenacityBrittle
Mohs scale hardness4 (defining mineral)
LusterVitreous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity3.175–3.184; to 3.56 if high in rare-earth elements
Optical propertiesIsotropic; weak anomalous anisotropism; moderate relief
Refractive index1.433–1.448
Fusibility3
Solubilityslightly water soluble and in hot hydrochloric acid
Other characteristicsMay be fluorescent, phosphorescent, thermoluminescent, and/or triboluminescent
References[2][3][4][5]

Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.

The Mohs scale of mineral hardness, based on scratch hardness comparison, defines value 4 as fluorite.[6]

Pure fluorite is colourless and transparent, both in visible and ultraviolet light, but impurities usually make it a colorful mineral and the stone has ornamental and lapidary uses. Industrially, fluorite is used as a flux for smelting, and in the production of certain glasses and enamels. The purest grades of fluorite are a source of fluoride for hydrofluoric acid manufacture, which is the intermediate source of most fluorine-containing fine chemicals. Optically clear transparent fluorite has anomalous partial dispersion, that is, its refractive index varies with the wavelength of light in a manner that differs from that of commonly used glasses, so fluorite is useful in making apochromatic lenses, and particularly valuable in photographic optics. Fluorite optics are also usable in the far-ultraviolet and mid-infrared ranges, where conventional glasses are too opaque for use. Fluorite also has low dispersion, and a high refractive index for its density.

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1990). "Fluorite". Handbook of Mineralogy (PDF). Vol. III (Halides, Hydroxides, Oxides). Chantilly, VA, US: Mineralogical Society of America. ISBN 0962209724. Archived (PDF) from the original on 2006-09-06. Retrieved December 5, 2011.
  3. ^ Cite error: The named reference Mindat was invoked but never defined (see the help page).
  4. ^ Fluorite. Webmineral.com
  5. ^ Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, pp. 324–325, 20th ed., ISBN 0-471-80580-7
  6. ^ Tabor, D. (1954). "Mohs's Hardness Scale - A Physical Interpretation". Proc. Phys. Soc. B. 67 (3): 249. Bibcode:1954PPSB...67..249T. doi:10.1088/0370-1301/67/3/310. Retrieved 19 January 2022.

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