Selenic acid

Selenic acid
Structural formula of selenic acid
Structural formula of selenic acid
Space-filling model of selenic acid
Space-filling model of selenic acid
Names
IUPAC name
Selenic(VI) acid
Other names
Selenic acid
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.072 Edit this at Wikidata
EC Number
  • 231-979-4
KEGG
RTECS number
  • VS6575000
UNII
UN number 1905
  • InChI=1S/H2O4Se/c1-5(2,3)4/h(H2,1,2,3,4) checkY
    Key: QYHFIVBSNOWOCQ-UHFFFAOYSA-N checkY
  • InChI=1/H2O4Se/c1-5(2,3)4/h(H2,1,2,3,4)
    Key: QYHFIVBSNOWOCQ-UHFFFAOYAI
  • O[Se+2]([O-])([O-])O
Properties
H2SeO4
Molar mass 144.9734 g/mol
Appearance Colorless deliquescent crystals
Density 2.95 g/cm3, solid
Melting point 58 °C (136 °F; 331 K)
Boiling point 260 °C (500 °F; 533 K) (decomposes)
130 g/(100 mL) (30 °C)
Acidity (pKa) pKa1 = −3
pKa2 = 1.9[1]
Conjugate base Biselenate
−51.2·10−6 cm3/mol
1.5174 (D-line, 20 °C)
Structure
tetrahedral at Se
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive, highly toxic
GHS labelling:[2]
GHS05: CorrosiveGHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Danger
H301, H315, H318, H331, H373, H410
P260, P261, P264, P270, P271, P273, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P310, P311, P314, P321, P330, P332+P313, P362, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
Related compounds
Other anions
selenious acid
hydrogen selenide
Other cations
sodium selenate
potassium selenate
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Selenic acid is the inorganic compound with the formula H2SeO4. It is an oxoacid of selenium, and its structure is more accurately described as O2Se(OH)2. It is a colorless compound. Although it has few uses, one of its salts, sodium selenate is used in the production of glass and animal feeds.[3]

  1. ^ Magdi Selim, H. (2011-03-15). Dynamics and Bioavailability of Heavy Metals in the Rootzone. CRC Press. ISBN 9781439826232.
  2. ^ "Selenic acid". pubchem.ncbi.nlm.nih.gov. Retrieved 16 December 2021.
  3. ^ Bernd E. Langner "Selenium and Selenium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a23_525.

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