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Zinc selenide

Zinc selenide
Zinc selenide
Names
Other names
Zinc selenide
Stilleite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.873 Edit this at Wikidata
EC Number
  • 215-259-7
UNII
  • InChI=1S/Se.Zn
    Key: SBIBMFFZSBJNJF-UHFFFAOYSA-N
  • zincblende structure: [SeH+2]12[ZnH2-2][SeH+2]3[ZnH2-2][SeH+2]([ZnH-2]14)[ZnH-2]1[Se+2]5([ZnH-2]38)[Zn-2]26[SeH+2]2[ZnH-2]([Se+2]4)[SeH+2]1[ZnH2-2][SeH+2]3[ZnH-2]2[Se+2][ZnH-2]([SeH+2]6[ZnH-2]([SeH+2])[SeH+2]68)[SeH+2]([ZnH2-2]6)[ZnH-2]35
  • wurtzite structure: [ZnH2-2]1[Se+2]47[ZnH-2]2[Se+2][ZnH-2]3[Se+2]8([ZnH2-2][SeH+2]([ZnH2-2]4)[ZnH2-2]6)[ZnH-2]4[Se+2][ZnH-2]5[Se+2]6([ZnH2-2]6)[Zn-2]78[Se+2]78[ZnH-2]([SeH+2]69)[SeH+2]5[ZnH2-2][SeH+2]4[ZnH-2]7[SeH+2]3[ZnH2-2][SeH+2]2[ZnH-2]8[SeH+2]1[ZnH2-2]9
  • wurtzite structure: [ZnH2-2]1[SeH+2]([ZnH2-2]6)[ZnH2-2][SeH+2]7[ZnH-2]2[Se+2][Zn-2]3([Se+2][ZnH-2]9[Se+2]5)[Se+2]18[Zn-2]45[Se+2][ZnH-2]5[SeH+2]6[Zn-2]78[Se+2]78[ZnH2-2][SeH+2]5[ZnH2-2][Se+2]4([ZnH2-2][SeH+2]9[ZnH2-2]4)[ZnH-2]7[Se+2]34[ZnH2-2][SeH+2]2[ZnH2-2]8
Properties
ZnSe
Molar mass 144.35 g/mol
Appearance light yellow solid
Density 5.27 g/cm3
Melting point 1,525 °C (2,777 °F)
negligible
Band gap 2.82 eV (10 K)
2.67 (550 nm)
2.40 (10.6 μm)
Structure
Zincblende (cubic)
a = 566.8 pm
Tetrahedral (Zn2+)
Tetrahedral (Se2−)
Thermochemistry
−177.6 kJ/mol
Hazards
GHS labelling:
GHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Danger
H301, H331, H373, H410
P260, P261, P264, P270, P271, P273, P301+P310, P304+P340, P311, P314, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions
 Zinc oxide
Zinc sulfide
Zinc telluride
Other cations
 Cadmium selenide
Mercury selenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Zinc selenide is the inorganic compound with the formula ZnSe. It is a lemon-yellow solid although most samples have a duller color due to the effects of oxidation. It is an intrinsic semiconductor with a band gap of about 2.70 eV at 25 °C (77 °F), equivalent to a wavelength of 459 nm. ZnSe occurs as the rare mineral stilleite, named after Hans Stille.

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