Thallium, 81Tl |
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Pronunciation | (THAL-ee-əm) |
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Appearance | silvery white |
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| [204.382, 204.385][1] |
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Atomic number (Z) | 81 |
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Group | group 13 (boron group) |
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Period | period 6 |
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Block | p-block |
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Electron configuration | [Xe] 4f14 5d10 6s2 6p1 |
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Electrons per shell | 2, 8, 18, 32, 18, 3 |
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Phase at STP | solid |
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Melting point | 577 K (304 °C, 579 °F) |
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Boiling point | 1746 K (1473 °C, 2683 °F) |
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Density (near r.t.) | 11.85 g/cm3 |
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when liquid (at m.p.) | 11.22 g/cm3 |
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Heat of fusion | 4.14 kJ/mol |
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Heat of vaporization | 165 kJ/mol |
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Molar heat capacity | 26.32 J/(mol·K) |
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Vapor pressure
P (Pa)
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1
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10
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100
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1 k
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10 k
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100 k
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at T (K)
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882
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977
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1097
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1252
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1461
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1758
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Oxidation states | −5,[2] −2, −1, +1, +2, +3 (a mildly basic oxide) |
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Electronegativity | Pauling scale: 1.62 |
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Ionization energies | - 1st: 589.4 kJ/mol
- 2nd: 1971 kJ/mol
- 3rd: 2878 kJ/mol
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Atomic radius | empirical: 170 pm |
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Covalent radius | 145±7 pm |
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Van der Waals radius | 196 pm |
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Spectral lines of thallium |
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Natural occurrence | primordial |
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Crystal structure | hexagonal close-packed (hcp) |
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Speed of sound thin rod | 818 m/s (at 20 °C) |
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Thermal expansion | 29.9 µm/(m⋅K) (at 25 °C) |
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Thermal conductivity | 46.1 W/(m⋅K) |
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Electrical resistivity | 0.18 µΩ⋅m (at 20 °C) |
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Magnetic ordering | diamagnetic[3] |
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Molar magnetic susceptibility | −50.9×10−6 cm3/mol (298 K)[4] |
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Young's modulus | 8 GPa |
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Shear modulus | 2.8 GPa |
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Bulk modulus | 43 GPa |
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Poisson ratio | 0.45 |
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Mohs hardness | 1.2 |
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Brinell hardness | 26.5–44.7 MPa |
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CAS Number | 7440-28-0 |
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Naming | after Greek thallos, green shoot or twig |
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Discovery | William Crookes (1861) |
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First isolation | Claude-Auguste Lamy (1862) |
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Category: Thallium | references |
Thallium is at chemical element, it has symbol Tl and atomic number 81. Its standard atomic weight is 204.4. It is found in Group 15 of the periodic table. Thallium is a soft, heavy and gray metal, but can look red due to oxidation. Thallium and its compounds are extremely toxic, even more than cyanide and arsenic.
- ↑ "Standard Atomic Weights: Thallium". CIAAW. 2009.
- ↑ Dong, Z.-C.; Corbett, J. D. (1996). "Na23K9Tl15.3: An Unusual Zintl Compound Containing Apparent Tl57−, Tl48−, Tl37−, and Tl5− Anions". Inorganic Chemistry. 35 (11): 3107–12. doi:10.1021/ic960014z. PMID 11666505.
- ↑ Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
- ↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
- ↑ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.