Tin, 00Sn |
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Allotropes | silvery-white, β (beta); gray, α (alpha) |
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Appearance | silvery-white (beta, β) or gray (alpha, α) |
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|
|
| 118.710(7)[1] |
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|
|
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Group | group 14 (carbon group) |
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Period | period 5 |
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Block | p-block |
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Electron configuration | [Kr] 4d10 5s2 5p2 |
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Electrons per shell | 2, 8, 18, 18, 4 |
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Phase at STP | solid |
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Melting point | 505.08 K (231.93 °C, 449.47 °F) |
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Boiling point | 2875 K (2602 °C, 4716 °F) |
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Density (near r.t.) | white, β: 7.265 g/cm3 gray, α: 5.769 g/cm3 |
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when liquid (at m.p.) | 6.99 g/cm3 |
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Heat of fusion | white, β: 7.03 kJ/mol |
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Heat of vaporization | white, β: 296.1 kJ/mol |
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Molar heat capacity | white, β: 27.112 J/(mol·K) |
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Vapor pressure
P (Pa)
|
1
|
10
|
100
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1 k
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10 k
|
100 k
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at T (K)
|
1497
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1657
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1855
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2107
|
2438
|
2893
|
|
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Oxidation states | −4, −3, −2, −1, 0,[2] +1,[3] +2, +3,[4] +4 (an amphoteric oxide) |
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Electronegativity | Pauling scale: 1.96 |
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Ionization energies | - 1st: 708.6 kJ/mol
- 2nd: 1411.8 kJ/mol
- 3rd: 2943.0 kJ/mol
-
|
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Atomic radius | empirical: 140 pm |
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Covalent radius | 139±4 pm |
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Van der Waals radius | 217 pm |
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Spectral lines of tin |
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Natural occurrence | primordial |
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Crystal structure | tetragonal white (β) |
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Crystal structure | face-centered diamond-cubic gray (α) |
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Speed of sound thin rod | 2730 m/s (at r.t.) (rolled) |
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Thermal expansion | 22.0 µm/(m⋅K) (at 25 °C) |
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Thermal conductivity | 66.8 W/(m⋅K) |
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Electrical resistivity | 115 nΩ⋅m (at 0 °C) |
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Magnetic ordering | gray: diamagnetic[5] white (β): paramagnetic |
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Molar magnetic susceptibility | (white) +3.1·10−6 cm3/mol (298 K)[6] |
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Young's modulus | 50 GPa |
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Shear modulus | 18 GPa |
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Bulk modulus | 58 GPa |
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Poisson ratio | 0.36 |
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Brinell hardness | 50–440 MPa |
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CAS Number | 7440-31-5 |
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Discovery | around 3500 BC |
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Symbol | "Sn": from Latin stannum |
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Main isotopes[7]
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Decay
|
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abundance
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half-life (t1/2)
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mode
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product
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112Sn
|
0.970%
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stable
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114Sn
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0.66%
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stable
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115Sn
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0.34%
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stable
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116Sn
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14.5%
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stable
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117Sn
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7.68%
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stable
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118Sn
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24.2%
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stable
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119Sn
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8.59%
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stable
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120Sn
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32.6%
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stable
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122Sn
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4.63%
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stable
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124Sn
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5.79%
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stable
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126Sn
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trace
|
2.3×105 y
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β−
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126Sb
| |
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Category: Tin | references |
Preview warning: unknown parameter "electron configuration"
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Preview warning: unknown parameter "isotopes comment"
Preview warning: unknown parameter "oxidation states"
Preview warning: unknown parameter "isotopes"
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Preview warning: unknown parameter "oxidation states comment"
Tin is a chemical element with symbol Sn (for Latin: stannum) and atomic number 50. It is in Group 14 on the periodic table. It has ten isotopes that are not radioactive, which is more than any other element.
- ↑ "Standard Atomic Weights: Tin". CIAAW. 1983.
- ↑ "New Type of Zero-Valent Tin Compound". Chemistry Europe. 27 August 2016.
- ↑ "HSn". NIST Chemistry WebBook. National Institute of Standards and Technology. Retrieved 23 January 2013.
- ↑ "SnH3". NIST Chemistry WebBook. National Institure of Standards and Technology. Retrieved 23 January 2013.
- ↑ Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
- ↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
- ↑ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ↑ "SnH3". NIST Chemistry WebBook. National Institure of Standards and Technology. Retrieved 23 January 2013.
- ↑ "HSn". NIST Chemistry WebBook. National Institute of Standards and Technology. Retrieved 23 January 2013.